Cryptic crossword No 101

Across

1. CO2's core parts denucleated for lower emissions (7)
2. Grant for long-suffering traveller (7)
3. Chat-show's top movie (4)
4. Desk's broken, unhinged and split (10)
5. Somewhere to browse for a loud, piercing outfit (6)
6. Cherish three Italian engineers, going around country in retirement (8)
7. Slug on flowering produce (6,3)
8. Wrestles over wife for clicks on YouTube (5)
9. Welsh journalist suggests what mole might receive (5)
10. Unknown site I get unexpectedly, with prevailing wind? (9)
11. At heart, groupies drive reason for floating (8)
12. Eating cooked dish (6)
13. Boring old holiday after CV mix-up (10)
14. Order car (4)
15. My new whale turned AWOL, perhaps (7)
16. Escorted popstar and editor (7)

Down

1. Country's air has rising Carbon Monoxide, with articles about dead (1,6)
2. Fare from spinning plates in Spain (5)
3. Easier to swallow raised exam grade (7)
4. Chills noodles (6)
5. Tinder splitting mechanism's glancing blow (9)
6. Supercilious Archer is intellectual, according to Cockney (7)
7. Writer urged interest in pieces! (8,5)
8. Up river next to church, I brewed oat drink (9)
9. Some itchy pox I caught, needing some fresh air (7)
10. Offensive tooter gets lockjaw (7)
11. City's present distribution agent takes extreme fee (5,2)
12. Sickened by half of quesadilla, refried slice of yam (6)
13. Blunder in front of boss (5)